Issue 39, 2013

Divergent reaction pathways of tris(oxazolinyl)borato zinc and magnesium silyl compounds

Abstract

Synthesis and reactivity of monomeric magnesium and zinc silyl compounds ToMM–Si(SiHMe2)3 and ToMM–Si(SiMe3)3 are described (ToM = tris(4,4-dimethyl-2-oxazolinyl)phenylborate). The magnesium compounds react slowly with water and air, while the zinc compounds are inert. With CO2, ToMMg–Si(SiHMe2)3 provides ToMMgO2CSi(SiHMe2)3 through CO2 insertion, whereas ToMZn–Si(SiHMe2)3 affords ToMZnOCHO.

Graphical abstract: Divergent reaction pathways of tris(oxazolinyl)borato zinc and magnesium silyl compounds

Supplementary files

Article information

Article type
Communication
Submitted
25 9月 2012
Accepted
16 11月 2012
First published
28 11月 2012

Chem. Commun., 2013,49, 4334-4336

Divergent reaction pathways of tris(oxazolinyl)borato zinc and magnesium silyl compounds

D. Mukherjee, N. L. Lampland, K. Yan, J. F. Dunne, A. Ellern and A. D. Sadow, Chem. Commun., 2013, 49, 4334 DOI: 10.1039/C2CC36953B

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