Issue 36, 2012

Investigating the effect of macrocycle size in anion templated imidazolium-based interpenetrated and interlocked assemblies

Abstract

The effect of varying the size of the macrocycle component on the formation of anion templated imidazolium interpenetrated assemblies is investigated. Two different approaches to reducing the macrocycle size are undertaken and the stabilities of the resulting pseudorotaxanes incorporating substituted imidazolium threading components studied using 1H NMR spectroscopy. Novel imidazolium axle containing interlocked rotaxane host structures are synthesised using chloride anion templated amide condensation and ‘stoppering’ methods, and the anion recognition properties of the ‘stoppered’ rotaxane investigated.

Graphical abstract: Investigating the effect of macrocycle size in anion templated imidazolium-based interpenetrated and interlocked assemblies

Supplementary files

Article information

Article type
Paper
Submitted
28 6月 2012
Accepted
24 7月 2012
First published
25 7月 2012

Org. Biomol. Chem., 2012,10, 7282-7291

Investigating the effect of macrocycle size in anion templated imidazolium-based interpenetrated and interlocked assemblies

G. T. Spence, N. G. White and P. D. Beer, Org. Biomol. Chem., 2012, 10, 7282 DOI: 10.1039/C2OB26237A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements