Volume 249, 2024

Water dynamics and sum-frequency generation spectra at electrode/aqueous electrolyte interfaces

Abstract

The dynamics of water at interfaces between an electrode and an electrolyte is essential for the transport of redox species and for the kinetics of charge transfer reactions next to the electrode. However, while the effects of electrode potential and ion concentration on the electric double layer structure have been extensively studied, a comparable understanding of dynamical aspects is missing. Interfacial water dynamics presents challenges since it is expected to result from the complex combination of water–water, water–electrode and water–ion interactions. Here we perform molecular dynamics simulations of aqueous NaCl solutions at the interface with graphene electrodes, and examine the impact of both ion concentration and electrode potential on interfacial water reorientational dynamics. We show that for all salt concentrations water dynamics exhibits strongly asymmetric behavior: it slows down at increasingly positively charged electrodes but it accelerates at increasingly negatively charged electrodes. At negative potentials water dynamics is determined mostly by the electrode potential value, but in contrast at positive potentials it is governed both by ion–water and electrode–water interactions. We show how these strikingly different behaviors are determined by the interfacial hydrogen-bond network structure and by the ions' surface affinity. Finally, we indicate how the structural rearrangements impacting water dynamics can be probed via vibrational sum-frequency generation spectroscopy.

Graphical abstract: Water dynamics and sum-frequency generation spectra at electrode/aqueous electrolyte interfaces

Associated articles

Article information

Article type
Paper
Submitted
17 5月 2023
Accepted
13 6月 2023
First published
14 6月 2023

Faraday Discuss., 2024,249, 289-302

Author version available

Water dynamics and sum-frequency generation spectra at electrode/aqueous electrolyte interfaces

J. Olivieri, J. T. Hynes and D. Laage, Faraday Discuss., 2024, 249, 289 DOI: 10.1039/D3FD00103B

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