Issue 62, 2022

Synthesis and optoelectronic properties of radical conjugated polyfluorenes

Abstract

A novel redox-active fluorene monomer is synthesized and copolymerized with 9,9-dioctylfluorene and benzo[c][1,2,5]thiadiazole via Suzuki cross-coupling to produce alternating and tertiary copolymers. Electrochemical and chemical reduction of the copolymers generates organic polymeric radical anions. Electrochemical, spectroscopic, and photophysical characterization grant insight into the structure–property relationship for open-shell conjugated polymers.

Graphical abstract: Synthesis and optoelectronic properties of radical conjugated polyfluorenes

Supplementary files

Article information

Article type
Communication
Submitted
06 5月 2022
Accepted
05 7月 2022
First published
14 7月 2022

Chem. Commun., 2022,58, 8630-8633

Synthesis and optoelectronic properties of radical conjugated polyfluorenes

S. Cheng, A. M. Battaglia, C. J. Imperiale, A. Lough, M. W. B. Wilson and D. S. Seferos, Chem. Commun., 2022, 58, 8630 DOI: 10.1039/D2CC02406C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements