Issue 58, 2022

Uniform wrapping of copper(i) oxide nanocubes by self-controlled copper-catalyzed azide–alkyne cycloaddition toward selective carbon dioxide electrocatalysis

Abstract

Copper(I) oxide nanocubes were wrapped with an extremely uniform organic layer grown by self-controlled, Cu-mediated catalysis. This layer aided in retaining the initial cubic structure of the copper nanocubes during their use as a CO2 reduction electrocatalyst, resulting in high CO2 reduction selectivity by strong suppression of hydrogen evolution because of exclusion of water from the surface.

Graphical abstract: Uniform wrapping of copper(i) oxide nanocubes by self-controlled copper-catalyzed azide–alkyne cycloaddition toward selective carbon dioxide electrocatalysis

Supplementary files

Article information

Article type
Communication
Submitted
08 4月 2022
Accepted
22 6月 2022
First published
23 6月 2022

Chem. Commun., 2022,58, 8053-8056

Uniform wrapping of copper(I) oxide nanocubes by self-controlled copper-catalyzed azide–alkyne cycloaddition toward selective carbon dioxide electrocatalysis

T. Umeda, T. Kurome, A. Sakatmoto, K. Kubo, T. Mizuta, S. U. Son and S. Kume, Chem. Commun., 2022, 58, 8053 DOI: 10.1039/D2CC02017C

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