Issue 21, 2018

DDQ-mediated regioselective C–S bond formation: efficient access to allylic sulfides

Abstract

A protocol for the synthesis of allylic sulfides from simple allylic hydrocarbons with thiophenol derivatives via a DDQ-mediated oxidative dehydrogenation strategy is described. This reaction possesses good functional group compatibility, broad substrate scope, and high atom- and step-economy. Moreover, the synthetic utility of this method can be highlighted by its application in the synthesis of versatile organo-sulfur compounds.

Graphical abstract: DDQ-mediated regioselective C–S bond formation: efficient access to allylic sulfides

Supplementary files

Article information

Article type
Research Article
Submitted
31 7月 2018
Accepted
15 9月 2018
First published
18 9月 2018

Org. Chem. Front., 2018,5, 3158-3162

DDQ-mediated regioselective C–S bond formation: efficient access to allylic sulfides

C. Li, J. Li, C. Tan, W. Wu and H. Jiang, Org. Chem. Front., 2018, 5, 3158 DOI: 10.1039/C8QO00799C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements