Programmed crystallization via epitaxial growth and ligand replacement towards hybridizing porous coordination polymer crystals

Kenji Hirai; Kebi Chen; Tomohiro Fukushima; Satoshi Horike; Mio Kondo; Nicolas Louvain; Chiwon Kim; Yoko Sakata; Mikhail Meilikhov; Osami Sakata; Susumu Kitagawa; Shuhei Furukawa

doi:10.1039/C3DT50679G

Programmed crystallizationvia epitaxial growth and ligand replacement towards hybridizing porous coordination polymer crystals†

Kenji Hirai,^a Kebi Chen,^a Tomohiro Fukushima,^a Satoshi Horike,^a Mio Kondo,^bc Nicolas Louvain,^bc Chiwon Kim,^a Yoko Sakata,^bc Mikhail Meilikhov,^b Osami Sakata,^d Susumu Kitagawa*^abc and Shuhei Furukawa*^bc

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^a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, Japan
E-mail: kitagawa@sbchem.kyoto-u.ac.jp
Fax: +81-75-383-2732
Tel: +81-75-383-2733

^b Institute for Integrated Cell-Material Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto, Japan
E-mail: shuhei.furukawa@icems.kyoto-u.ac.jp
Fax: +81-75-753-9820
Tel: +81-75-753-9868

^c ERATO Kitagawa Integrated Pores Project, Japan Science and Technology Agency (JST), Kyoto Research Park bldg #3, Shimogyo-ku, Kyoto, Japan

^d Synchrotron X-ray Station at Spring-8, National Institute for Materials Science (NIMS), Sayo, Hyogo 679-5148, Japan

Abstract

Hybridized porous coordination polymers (PCPs) are synthesized through epitaxial growth or ligand replacement. Whereas epitaxial growth on the core crystal leads to a sandwich type PCP, ligand replacement near the surface of core crystal results in a core–shell type PCP.

This article is part of the themed collections: MOFs: Three Decades of Design and Discovery and Coordination Programming: Science of Molecular Superstructures Towards Chemical Devices

Dalton Transactions

Programmed crystallizationvia epitaxial growth and ligand replacement towards hybridizing porous coordination polymer crystals†

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Programmed crystallization via epitaxial growth and ligand replacement towards hybridizing porous coordination polymer crystals

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