Issue 21, 2022

Photobase-catalysed anionic thiol-epoxy click photopolymerization under NIR irradiation: from deep curing to shape memory

Abstract

Several unimolecular photobase generators capable of catalyzing upconversion nanoparticle-assisted anionic thiol-epoxy click photopolymerization are presented. The fabricated polymers, with a curing depth of 11.8 cm, are dual-wavelength responsive and display shape memory function, showing great potential for the construction of smart medical devices and robots.

Graphical abstract: Photobase-catalysed anionic thiol-epoxy click photopolymerization under NIR irradiation: from deep curing to shape memory

Supplementary files

Article information

Article type
Communication
Submitted
31 1月 2022
Accepted
01 4月 2022
First published
04 4月 2022

Polym. Chem., 2022,13, 3048-3052

Photobase-catalysed anionic thiol-epoxy click photopolymerization under NIR irradiation: from deep curing to shape memory

Y. Huang, L. Li, X. Liu and Z. Li, Polym. Chem., 2022, 13, 3048 DOI: 10.1039/D2PY00144F

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