Issue 75, 2012
From the journal:

Chemical Communications

Functional group effects on metal–organic framework topology†‡

Phuong V. Dau,a   Kristine K. Tanabea  and  Seth M. Cohen*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA, USA 92093
E-mail: scohen@ucsd.edu

Abstract

Functionalization of the ligand 1,3,5-tris(4-carboxyphenyl)benzene (H3BTB) has been realized with methoxy (H3BTB–[OMe]3) and hydroxy (H3BTB–[OH]3) groups. Combining H3BTB–[OMe]3 and Zn(II) results in the formation of the first isostructural, functionalized analogue of MOF-177 (MOF-177–OMe), while the combination of H3BTB–[OH]3 and Zn(II) generates a rare, interpenetrated pcu-e framework.

Graphical abstract: Functional group effects on metal–organic framework topology

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC34938H
Article type
Communication
Submitted
11 7月 2012
Accepted
07 8月 2012
First published
08 8月 2012

Chem. Commun., 2012,48, 9370-9372

Permissions

Request permissions

Functional group effects on metal–organic framework topology

P. V. Dau, K. K. Tanabe and S. M. Cohen, Chem. Commun., 2012, 48, 9370 DOI: 10.1039/C2CC34938H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements