Issue 69, 2012

[(η2-(Si/Ge)4)Zn(η2-(Si/Ge)4)]6− – novel Zintl clusters with mixed Si/Ge tetrahedra bridged by a Zn atom

Abstract

The solubility of the ternary Zintl phase K12Si17−xGex (x = 5), containing mixed group 14 element clusters, was investigated. Novel dimeric tetrahedral Zintl clusters [(η2-E4)Zn(η2-E4)]6− with mixed site occupation (E = Si/Ge) were obtained through reaction with (C6H6)2Zn in ammonia solutions and investigated by means of X-ray single crystal diffraction.

Graphical abstract: [(η2-(Si/Ge)4)Zn(η2-(Si/Ge)4)]6− – novel Zintl clusters with mixed Si/Ge tetrahedra bridged by a Zn atom

Supplementary files

Article information

Article type
Communication
Submitted
18 4月 2012
Accepted
10 7月 2012
First published
11 7月 2012

Chem. Commun., 2012,48, 8676-8678

[(η2-(Si/Ge)4)Zn(η2-(Si/Ge)4)]6− – novel Zintl clusters with mixed Si/Ge tetrahedra bridged by a Zn atom

M. Waibel, T. Henneberger, L. Jantke and T. F. Fässler, Chem. Commun., 2012, 48, 8676 DOI: 10.1039/C2CC33652A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements