Issue 25, 2009
From the journal:

Journal of Materials Chemistry

Enhanced H2adsorption enthalpy in the low-surface area, partially fluorinated coordination polymer Zn5(triazole)6(tetrafluoroterephthalate)2(H2O)2·4H2O†‡

Zeric Hulvey,a   Eduardo H. L. Falcao,a   Juergen Eckerta  and  Anthony K. Cheetham*b  

* Corresponding authors

a Materials Research Laboratory, University of California, Santa Barbara, CA, USA
E-mail: zhulvey@chem.ucsb.edu

b Department of Materials Science and Metallurgy, University of Cambridge, Pembroke Street, Cambridge, UK
E-mail: akc30@cam.ac.uk

Abstract

A porous coordination polymer containing zinc, 1,2,4-triazolate, and tetrafluoroterephthalate displays a high physisorptive hydrogen adsorption enthalpy of 8 kJ/mol, as a result of fluorine atoms exposed to the pore surface and the structure's small pore size.

Graphical abstract: Enhanced H2 adsorption enthalpy in the low-surface area, partially fluorinated coordination polymer Zn5(triazole)6(tetrafluoroterephthalate)2(H2O)2·4H2O

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B900879A
Article type
Communication
Submitted
15 1月 2009
Accepted
09 3月 2009
First published
19 3月 2009

J. Mater. Chem., 2009,19, 4307-4309

Permissions

Request permissions

Enhanced H2 adsorption enthalpy in the low-surface area, partially fluorinated coordination polymer Zn5(triazole)6(tetrafluoroterephthalate)2(H2O)2·4H2O

Z. Hulvey, E. H. L. Falcao, J. Eckert and A. K. Cheetham, J. Mater. Chem., 2009, 19, 4307 DOI: 10.1039/B900879A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements