Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L)4RuCl2]2+ and [Pd(μ-L)4Pt]4+ cage architectures

Hayden B. Gearing; Tilo Söhnel; Paul Young; Lynn Lisboa; L. James Wright; James D. Crowley; Christian G. Hartinger

doi:10.1039/D4CC03613A

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Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L)₄RuCl₂]²⁺ and [Pd(μ-L)₄Pt]⁴⁺ cage architectures†

Hayden B. Gearing,^a Tilo Söhnel,

^ab Paul Young,

^c Lynn Lisboa,^d L. James Wright,

^a James D. Crowley

^bd and Christian G. Hartinger

*^a

Author affiliations

* Corresponding authors

^a School of Chemical Sciences, University of Auckland, Private Bag 92019, Auckland 1142, New Zealand
E-mail: c.hartinger@auckland.ac.nz

^b MacDiarmid Institute for Advanced Materials and Nanotechnology, Victoria University of Wellington, PO Box 600, Wellington 6140, New Zealand

^c School of Biological Sciences, University of Auckland, Private Bag 92019, Auckland 1142, New Zealand

^d Department of Chemistry, University of Otago, PO Box 56, Dunedin 9054, New Zealand

Abstract

Heterobimetallic cages built from Pd and either octahedral Ru or square-planar Pt moieties and bridged by ligands with H bonding-accepting or -donating properties are reported. They showed stimulus-responsive dis- and reassembly, while guest binding was found to be dependent on the complementary properties of the guest to the host in terms of charge, size and H bonding properties.

This article is part of the themed collection: ChemComm 60th Anniversary Collection

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Article information

DOI: https://doi.org/10.1039/D4CC03613A
Article type: Communication
Submitted: 19 7月 2024
Accepted: 30 8月 2024
First published: 30 8月 2024

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Chem. Commun., 2024,60, 10950-10953

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Modulating the guest binding ability within mixed-coordination geometry [Pd(μ-L)₄RuCl₂]²⁺ and [Pd(μ-L)₄Pt]⁴⁺ cage architectures

H. B. Gearing, T. Söhnel, P. Young, L. Lisboa, L. J. Wright, J. D. Crowley and C. G. Hartinger, Chem. Commun., 2024, 60, 10950 DOI: 10.1039/D4CC03613A

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