Tetraphenylpentalenide organolanthanide complexes

Nicholas J. Katzer; Mandeep Kaur; Asmita Sen; Rupal Nimaiyar; Jochen Autschbach; Polly L. Arnold; Ulrich Hintermair

doi:10.1039/D4CC02570A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Tetraphenylpentalenide organolanthanide complexes†

Nicholas J. Katzer,

‡^ab Mandeep Kaur,

‡^c Asmita Sen,

‡^d Rupal Nimaiyar,^a Jochen Autschbach,

*^d Polly L. Arnold

*^ab and Ulrich Hintermair

*^c

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of California, Berkeley, CA, USA
E-mail: pla@berkeley.edu

^b Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

^c Department of Chemistry, University of Bath, UK
E-mail: u.hintermair@bath.ac.uk

^d Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260, USA
E-mail: jochena@buffalo.edu

Abstract

The D_2h symmetrical 1,3,4,6-tetraphenylpentalenide is an excellent ligand for the stabilisation of strongly coloured bis(pentalenide) Ln^III sandwich complexes. These easily accessible compounds complement previously reported lanthanide organometallics and provide new opportunities to understand the roles of the f-orbitals in electronic structure and bonding.

This article is part of the themed collections: Chemical Communications HOT Articles 2024 and 2024 Pioneering Investigators

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/D4CC02570A
Article type: Communication
Submitted: 27 5月 2024
Accepted: 08 7月 2024
First published: 12 7月 2024
This article is Open Access

Download Citation

Chem. Commun., 2024,60, 9749-9752

Permissions

Request permissions

Tetraphenylpentalenide organolanthanide complexes

N. J. Katzer, M. Kaur, A. Sen, R. Nimaiyar, J. Autschbach, P. L. Arnold and U. Hintermair, Chem. Commun., 2024, 60, 9749 DOI: 10.1039/D4CC02570A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Tetraphenylpentalenide organolanthanide complexes†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Tetraphenylpentalenide organolanthanide complexes

Social activity

Search articles by author

Spotlight

Advertisements