Bis(di-tert-butylindenyl)tetrelocenes

Liane Hildegard Staub; Jessica Lambert; Carsten Müller; Bernd Morgenstern; Michael Zimmer; Joshua Warken; Aylin Koldemir; Theresa Block; Rainer Pöttgen; André Schäfer

doi:10.1039/D2DT00582D

Bis(di-tert-butylindenyl)tetrelocenes†

Liane Hildegard Staub,‡^a Jessica Lambert,‡^a Carsten Müller,^a Bernd Morgenstern,^a Michael Zimmer,^a Joshua Warken,^a Aylin Koldemir,^b Theresa Block,^b Rainer Pöttgen

^b and André Schäfer

*^a

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^a Department of Chemistry, Faculty of Natural Sciences and Technology, Saarland University, Campus Saarbrücken, 66123 Saarbrücken, Germany
E-mail: andre.schaefer@uni-saarland.de

^b Institute of Inorganic and Analytical Chemistry, Westfälische Wilhelms-Universität Münster, Corrensstrasse 30, 48149 Münster, Germany

Abstract

The synthesis and characterization of bis(di-tert-butylindenyl) germanium(II), tin(II) and lead(II) complexes are reported, which includes the first structurally authenticated example of a bis(indenyl)germanocene. The species were studied in detail in solution and in the solid, which includes single crystal X-ray diffraction and NMR spectroscopy, as well as Mössbauer spectroscopy of the tin compound.

This article is part of the themed collections: New Talent: Europe and Dalton Transactions up-and-coming articles

Dalton Transactions

Bis(di-tert-butylindenyl)tetrelocenes†

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