Six-coordinated dinuclear lanthanide(iii) amide complexes: investigation of magnetization relaxation dynamics and their electronic structures

Abstract

A series of rare six-coordinated dinuclear Ln(III) complexes [Ln₂(μ-Cl)₂Cl₄Li₂(L)₂(THF)₆] were structurally characterized using a bulky amide ligand (L; Ln = Gd(1), Dy(2) and Y(3)). Detailed magnetic studies disclose that a weak antiferromagnetic coupling exists within 1 (−0.09 cm⁻¹) and 2 (−0.07 cm⁻¹; −2J Hamiltonian). Additionally, this study unveils the importance of the amide ligand at the coordination site of Dy(III), which manifests a slow relaxation of magnetization in the absence of an external magnetic field. This has been rationalized by detailed ab initio calculations as well as the electronic structure determination of 1 and 2.