Thermally stable zinc hydride catalyst for hydrosilylation of CO2 to silyl formate at atmospheric pressure

Abstract

Neutral zinc complexes supported by H[PNNO], a diaminophenolate ligand bearing a pendant phosphine group, were synthesized and characterized. The phosphine arm adopts two different configurations in solution and prevents aggregation. The monomeric zinc hydride complex is stable at elevated temperatures up to 125 °C and reacts readily with CO₂ to afford a zinc formate complex. The zinc hydride is active for CO₂ hydrosilylation at atmospheric CO₂ pressure and is selective for CO₂ reduction to the silyl-formate product.