Issue 5, 2020

Dynamical evolution of the 2D/3D interface: a hidden driver behind perovskite solar cell instability

Abstract

Engineering two-/three-dimensional (2D/3D) perovskite solar cells is nowadays a popular strategy for efficient and stable devices. However, the exact function of the 2D/3D interface in controlling the long-term device behavior is still obscure. Here, we reveal a dynamical structural mutation of the 2D/3D interface: the small cations in the 3D cage move towards the 2D layer, which acts as an ion scavenger. If structurally stable, the 2D layer physically blocks the ion movement at the interface boosting the device stability. Otherwise, the 2D layer embeds them, dynamically self-transforming into a quasi-2D structure. The judicious choice of the 2D constituent is decisive in controlling the 2D/3D kinetics and improving the device lifetime, opening a new avenue for perovskite interface design.

Graphical abstract: Dynamical evolution of the 2D/3D interface: a hidden driver behind perovskite solar cell instability

Supplementary files

Article information

Article type
Communication
Submitted
13 11月 2019
Accepted
31 12月 2019
First published
03 1月 2020

J. Mater. Chem. A, 2020,8, 2343-2348

Dynamical evolution of the 2D/3D interface: a hidden driver behind perovskite solar cell instability

A. A. Sutanto, N. Drigo, V. I. E. Queloz, I. Garcia-Benito, A. R. Kirmani, L. J. Richter, P. A. Schouwink, K. T. Cho, S. Paek, M. K. Nazeeruddin and G. Grancini, J. Mater. Chem. A, 2020, 8, 2343 DOI: 10.1039/C9TA12489F

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