Issue 26, 2019

Energetics and ionization dynamics of two diarylketone molecules: benzophenone and fluorenone

Abstract

Single photon ionization and subsequent unimolecular ion decomposition were studied on jet-cooled benzophenone and fluorenone separately, using VUV synchrotron radiation in a photoion/photoelectron coincidence setup. Slow PhotoElectron Spectra (SPES) were recorded in coincidence with either the parent or the fragment ions for < 12.5 eV. Dissociative ionization is observed for benzophenone only. The full interpretation of the measurements, including the identification of the neutral and ionic species when dissociative ionization is at play, benefits from high level ab initio computations for determining the equilibrium structures and the energetics of the neutral and ionized molecules and of their fragments. Electronically excited states of the parent molecular ions were calculated also. From this analysis, an accurate experimental determination of the energetics of the benzophenone and fluorenone ions and of their fragmentation channels is available: adiabatic ionization energies of benzophenone at 8.923 ± 0.005 eV and of fluorenone at 8.356 ± 0.007 eV; and appearance energies of benzophenone fragment ions at 11.04 ± 0.02 eV (loss of C6H5), 11.28 ± 0.02 eV (loss of H) and 11.45 ± 0.02 eV (loss of CO). The corresponding fragmentation mechanisms are explored, showing likely concerted bonds rearrangement. Possible pre-ionizing fragmentation is discussed in light of the spectra presented. The structural rigidity of fluorenone diarylketone seems to be the origin of the inhibition of the fragmentation of its cation.

Graphical abstract: Energetics and ionization dynamics of two diarylketone molecules: benzophenone and fluorenone

Supplementary files

Article information

Article type
Paper
Submitted
26 4月 2019
Accepted
06 6月 2019
First published
06 6月 2019

Phys. Chem. Chem. Phys., 2019,21, 14453-14464

Energetics and ionization dynamics of two diarylketone molecules: benzophenone and fluorenone

Z. Gouid, A. Röder, B. K. Cunha de Miranda, M. Gaveau, M. Briant, B. Soep, J. Mestdagh, M. Hochlaf and L. Poisson, Phys. Chem. Chem. Phys., 2019, 21, 14453 DOI: 10.1039/C9CP02385B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements