Synthesis of o-carborane-functionalized metal–organic frameworks through ligand exchanges for aggregation-induced emission in the solid state

Sangdon Choi; Ha-Eun Lee; Chan Hee Ryu; Jooyeon Lee; Jihyun Lee; Minyoung Yoon; Youngjo Kim; Myung Hwan Park; Kang Mun Lee; Min Kim

doi:10.1039/C9CC06386B

Synthesis of o-carborane-functionalized metal–organic frameworks through ligand exchanges for aggregation-induced emission in the solid state†

Sangdon Choi,‡^a Ha-Eun Lee,‡^a Chan Hee Ryu,‡^b Jooyeon Lee,^a Jihyun Lee,^c Minyoung Yoon,

^d Youngjo Kim,

^a Myung Hwan Park,

*^e Kang Mun Lee

*^b and Min Kim

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and BK21Plus Research Team, Chungbuk National University, Cheongju, Korea
E-mail: minkim@chungbuk.ac.kr

^b Department of Chemistry, Institute of Molecular Science and Fusion Technology, Kangwon National University, Chuncheon 24341, Korea
E-mail: kangmunlee@kangwon.ac.kr

^c Department of Nanochemistry, Gachon University, Sungnam 13120, Korea

^d Department of Chemistry, Kyungpook National University, Daegu 41566, Korea

^e Department of Chemistry Education, Chungbuk National University, Cheongju, Korea
E-mail: mhpark98@chungbuk.ac.kr

Abstract

The carborane (CB)-functionalized ligand was installed in a variety of MOFs through postsynthetic ligand exchange processes. This methodology is a general method for preparing o-CB-functionalized MOFs with known frameworks. Furthermore, the photoluminescence (PL) spectra revealed intriguing aggregation-induced emission (AIE) features following the systematic incorporation of o-CB functionalities into framework-type materials.

This article is part of the themed collection: Celebrating the 75th Anniversary of the Korean Chemical Society (KCS)

Chemical Communications

Synthesis of o-carborane-functionalized metal–organic frameworks through ligand exchanges for aggregation-induced emission in the solid state†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Synthesis of o-carborane-functionalized metal–organic frameworks through ligand exchanges for aggregation-induced emission in the solid state

Social activity

Search articles by author

Spotlight

Advertisements