Issue 24, 2016

Permanently porous hydrogen-bonded frameworks of rod-like thiophenes, selenophenes, and tellurophenes capped with MIDA boronates

Abstract

Permanently porous hydrogen-bonded organic frameworks comprising rod-like molecules with two MIDA boronate termini have been prepared. We show that MIDA boronates self-assemble through multiple hydrogen-bonding interactions. Thiophene-containing frameworks are fluorescent and have a 6.6% absolute quantum yield. The approach appears to be general and introduces new design rules for constructing hydrogen-bonded organic frameworks.

Graphical abstract: Permanently porous hydrogen-bonded frameworks of rod-like thiophenes, selenophenes, and tellurophenes capped with MIDA boronates

Supplementary files

Article information

Article type
Communication
Submitted
21 12月 2015
Accepted
22 12月 2015
First published
05 1月 2016
This article is Open Access
Creative Commons BY license

Dalton Trans., 2016,45, 9754-9757

Permanently porous hydrogen-bonded frameworks of rod-like thiophenes, selenophenes, and tellurophenes capped with MIDA boronates

P. Li, C. Qian, A. J. Lough, G. A. Ozin and D. S. Seferos, Dalton Trans., 2016, 45, 9754 DOI: 10.1039/C5DT04960A

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