Issue 52, 2012

Transmetallation reactions of a lithium disilenide

Abstract

The first magnesium, copper and zinc disilenides were prepared via transmetallation reactions of a lithium disilenide and structurally characterised. The copper and zinc derivatives show red-shifted UV/vis absorptions due to admixture of metal d-orbitals to the highest occupied molecular orbital.

Graphical abstract: Transmetallation reactions of a lithium disilenide

Supplementary files

Article information

Article type
Communication
Submitted
27 4月 2012
Accepted
09 5月 2012
First published
09 5月 2012

Chem. Commun., 2012,48, 6595-6597

Transmetallation reactions of a lithium disilenide

M. J. Cowley, K. Abersfelder, A. J. P. White, M. Majumdar and D. Scheschkewitz, Chem. Commun., 2012, 48, 6595 DOI: 10.1039/C2CC33047D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements