Issue 7, 2010
From the journal:

Chemical Communications

Hydrolysis of 2-phenylazophenyltellurium trihalides: isolation of an unprecedented homometallic, discrete heptanuclear organotellurium oxidecluster†

Kriti Srivastava,a   Sagar Sharma,a   Harkesh B. Singh,*a   Udai P. Singhb  and  Ray J. Butcherc  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Bombay, Powai, India
E-mail: chhbsia@chem.iitb.ac.in
Fax: +91 22 2572 3480
Tel: +91 22 2576 7190

b Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247667, India

c Department of Chemistry, Howard University, Washington, USA

Abstract

Alkaline hydrolysis of RTeBr3 (R = 2-phenylazophenyl) gave intramolecularly stabilized homometallic, heptanuclear organotellurium oxide cluster R6Te7O11 (4) in good yield.

Graphical abstract: Hydrolysis of 2-phenylazophenyltellurium trihalides: isolation of an unprecedented homometallic, discrete heptanuclear organotellurium oxide cluster

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Article information

DOI
https://doi.org/10.1039/B921785A
Article type
Communication
Submitted
19 10月 2009
Accepted
24 11月 2009
First published
17 12月 2009

Chem. Commun., 2010,46, 1130-1132

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Hydrolysis of 2-phenylazophenyltellurium trihalides: isolation of an unprecedented homometallic, discrete heptanuclear organotellurium oxide cluster

K. Srivastava, S. Sharma, H. B. Singh, U. P. Singh and R. J. Butcher, Chem. Commun., 2010, 46, 1130 DOI: 10.1039/B921785A

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