Spin crossover {[Fe(atrz)3](OTs)2}n monolith: a green synthesis approach for Robust switchable materials†
David
Fairen-Jimenez 
*b
and
José
Sánchez Costa
*a
*b
and
José
Sánchez Costa
*a
Abstract
This work presents a straightforward, room-temperature synthesis of a robust {[Fe(atrz)3](OTs)2}n monolith. This approach offers a green alternative to traditional nanoparticle synthesis for manipulating spin crossover (SCO) behaviour. The monolith exhibits a more gradual SCO transition at lower temperatures compared to the bulk material, aligning with observations in smaller particle systems. Notably, the synthesis employs a solvent- and surfactant-free approach, simplifying the process and potentially reducing environmental impact, aligning with the principles of green chemistry.
2}n monolith: a green synthesis approach for Robust switchable materials](/zh-CN/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=D4DT00684D&imageInfo.ImageIdentifier.Year=2024)
- This article is part of the themed collection: Recent progress and perspectives on spin transition compounds
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