The importance of crystal size for breathing kinetics in MIL-53(Al)

Volodymyr Bon; Nikita Busov; Irena Senkovska; Nadine Bönisch; Leila Abylgazina; Azat Khadiev; Dmitri Novikov; Stefan Kaskel

doi:10.1039/D2CC02662G

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The importance of crystal size for breathing kinetics in MIL-53(Al)†

Volodymyr Bon,

*^a Nikita Busov,‡^a Irena Senkovska,

^a Nadine Bönisch,^a Leila Abylgazina,^a Azat Khadiev,^b Dmitri Novikov^b and Stefan Kaskel

*^a

Author affiliations

* Corresponding authors

^a Chair of Inorganic Chemistry I, Technische Universität Dresden, Bergstraße 66, 01069 Dresden, Germany
E-mail: volodymyr.bon@tu-dresden.de, stefan.kaskel@tu-dresden.de

^b P23 group, Petra III Synchrotron, DESY, Notkestraße 85, 22607, Hamburg, Germany

Abstract

Herein we analyze the switching kinetics of a breathing framework MIL-53(Al) with respect to different crystallite size regimes. Synchrotron time-resolved powder X-ray diffraction (PXRD) and adsorption rate analysis of n-butane physisorption at 298 K demonstrate the decisive role of crystal size affecting the time domain of breathing transitions in MIL-53(Al).

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Article information

DOI: https://doi.org/10.1039/D2CC02662G
Article type: Communication
Submitted: 10 5月 2022
Accepted: 29 7月 2022
First published: 22 8月 2022

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Chem. Commun., 2022,58, 10492-10495

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The importance of crystal size for breathing kinetics in MIL-53(Al)

V. Bon, N. Busov, I. Senkovska, N. Bönisch, L. Abylgazina, A. Khadiev, D. Novikov and S. Kaskel, Chem. Commun., 2022, 58, 10492 DOI: 10.1039/D2CC02662G

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Chemical Communications

The importance of crystal size for breathing kinetics in MIL-53(Al)†

Abstract

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The importance of crystal size for breathing kinetics in MIL-53(Al)

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