Issue 36, 2021

Recent developments in catalytic cross-couplings with unsaturated carboxylates

Abstract

Catalytic cross-couplings through C–O bond-cleavage of unsaturated carboxylates with organometallics have emerged as a powerful method for sustainable syntheses. Over the last decade, remarkable achievements have been made with the development of transition metal-catalyzed cross-couplings with the readily available phenol and enol derivatives as suitable coupling electrophiles beyond unsaturated halides. Therefore, this perspective describes the recent advances in the field of transition metal-catalyzed C–O bond activation of unsaturated carboxylates with organometallics, including B, Mg, Zn, Al, and Si reagents, until May 2021.

Graphical abstract: Recent developments in catalytic cross-couplings with unsaturated carboxylates

Article information

Article type
Review Article
Submitted
17 5月 2021
Accepted
09 8月 2021
First published
09 8月 2021

Org. Biomol. Chem., 2021,19, 7754-7767

Recent developments in catalytic cross-couplings with unsaturated carboxylates

Y. Hu, B. Hu, X. Liu, Z. Ren and J. Li, Org. Biomol. Chem., 2021, 19, 7754 DOI: 10.1039/D1OB00955A

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