Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np6O8} hexanuclear clusters

N. P. Martin; J. März; H. Feuchter; S. Duval; P. Roussel; N. Henry; A. Ikeda-Ohno; T. Loiseau; C. Volkringer

doi:10.1039/C8CC03121E

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np₆O₈} hexanuclear clusters†

N. P. Martin,

^a J. März,^b H. Feuchter,^a S. Duval,^a P. Roussel,^a N. Henry,^a A. Ikeda-Ohno,

^b T. Loiseau

^a and C. Volkringer

*^ac

Author affiliations

* Corresponding authors

^a Université de Lille, Centrale Lille, ENSCL, Univ. Artois, UMR CNRS 8181-UCCS-Unité de Catalyse et Chimie du Solide, 59000 Lille, France
E-mail: christophe.volkringer@ensc-lille.fr

^b Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Institute of Resource Ecology, Bautzner Landstrasse 400, 01328 Dresden, Germany

^c Institut Universitaire de France, 1 rue Descartes, 75231 Paris Cedex 05, France

Abstract

Successful synthesis of the first transuranium metal–organic frameworks (TRU-MOFs) involving tetravalent Np⁴⁺ is reported. These compounds were obtained from the controlled hydrolysis of Np⁴⁺ in the presence of dicarboxylate ligands. The final structures contain the [Np₆O₄(OH)₄(H₂O)₆]¹²⁺ unit, which were never crystallized before with tetravalent neptunium, associated with ditopic ligands.

This article is part of the themed collection: New molecules and materials from the f-block

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C8CC03121E
Article type: Communication
Submitted: 18 4月 2018
Accepted: 16 5月 2018
First published: 16 5月 2018

Download Citation

Chem. Commun., 2018,54, 6979-6982

Permissions

Request permissions

Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np₆O₈} hexanuclear clusters

N. P. Martin, J. März, H. Feuchter, S. Duval, P. Roussel, N. Henry, A. Ikeda-Ohno, T. Loiseau and C. Volkringer, Chem. Commun., 2018, 54, 6979 DOI: 10.1039/C8CC03121E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications