Issue 40, 2014
From the journal:

Chemical Communications

Rhodium-catalyzed carbene transfer to alkynes via 2-furylcarbenes generated from enynones†‡

María J. González,a   Enol Lópeza  and  Rubén Vicente*a  

* Corresponding authors

a Departamento de Química Orgánica e Inorgánica and Instituto Universitario de Química Organometálica “Enrique Moles”, Universidad de Oviedo, c/Julián Clavería 8, 33006-Oviedo, Spain
E-mail: vicenteruben@uniovi.es
Fax: +34 985103450
Tel: +34 985103075

Abstract

A rhodium-catalyzed carbene transfer to alkynes is reported. Easily available enynones served as the carbene source replacing diazocompounds. The overall process involved a cyclization–cyclopropenation–ring enlargement sequence.

Graphical abstract: Rhodium-catalyzed carbene transfer to alkynes via 2-furylcarbenes generated from enynones

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC47481J
Article type
Communication
Submitted
30 9月 2013
Accepted
15 10月 2013
First published
17 10月 2013

Chem. Commun., 2014,50, 5379-5381

Permissions

Request permissions

Rhodium-catalyzed carbene transfer to alkynes via 2-furylcarbenes generated from enynones

M. J. González, E. López and R. Vicente, Chem. Commun., 2014, 50, 5379 DOI: 10.1039/C3CC47481J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements