Issue 5, 2016

C(sp3)–H bond functionalization by sequential hydride transfer/cyclization: electronic effect and steric effect controlled regioselectivity

Abstract

The electronic effect and steric effect have a dramatic impact on the fascinating cascade [1,n]-hydride transfer/cyclization. The regioselectivity of two potential hydrogen donors could be perfectly tuned to construct different skeletons.

Graphical abstract: C(sp3)–H bond functionalization by sequential hydride transfer/cyclization: electronic effect and steric effect controlled regioselectivity

Article information

Article type
Highlight
Submitted
27 ⵉⵏⵏ 2016
Accepted
03 ⵎⴰⵕ 2016
First published
03 ⵎⴰⵕ 2016

Org. Chem. Front., 2016,3, 635-638

Author version available

C(sp3)–H bond functionalization by sequential hydride transfer/cyclization: electronic effect and steric effect controlled regioselectivity

L. Wang and J. Xiao, Org. Chem. Front., 2016, 3, 635 DOI: 10.1039/C6QO00043F

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