Issue 6, 2016

Facet-dependent catalytic activity of ZIF-8 nanocubes and rhombic dodecahedra based on tracing substrate diffusion in pores by SERS: a case study for surface catalysis of MOFs

Abstract

We employed ZIF-8 rhombic dodecahedra and nanocubes as catalysts to obtain insights into the surface catalysis of MOFs based on facet-dependent catalytic activity for Knoevenagel condensation. The location of catalytic reactions was identified by using spiky Au@ZIF-8 single-core structures as surface-enhanced Raman scattering active substrates for aldehyde detection.

Graphical abstract: Facet-dependent catalytic activity of ZIF-8 nanocubes and rhombic dodecahedra based on tracing substrate diffusion in pores by SERS: a case study for surface catalysis of MOFs

Supplementary files

Article information

Article type
Communication
Submitted
03 ⵏⵓⵡ 2015
Accepted
05 ⴱⵕⴰ 2016
First published
08 ⴱⵕⴰ 2016

Catal. Sci. Technol., 2016,6, 1616-1620

Author version available

Facet-dependent catalytic activity of ZIF-8 nanocubes and rhombic dodecahedra based on tracing substrate diffusion in pores by SERS: a case study for surface catalysis of MOFs

L. Chen, B. Duan, Q. Luo, Z. Gu, J. Liu and C. Duan, Catal. Sci. Technol., 2016, 6, 1616 DOI: 10.1039/C5CY01882J

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