Halogen bonding-enhanced electrochemical halide anion sensing by redox-active ferrocene receptors

Jason Y. C. Lim; Matthew J. Cunningham; Jason J. Davis; Paul D. Beer

doi:10.1039/C5CC05704C

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Halogen bonding-enhanced electrochemical halide anion sensing by redox-active ferrocene receptors†

Jason Y. C. Lim,^a Matthew J. Cunningham,^b Jason J. Davis^b and Paul D. Beer*^a

Author affiliations

* Corresponding authors

^a Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, UK
E-mail: paul.beer@chem.ox.ac.uk

^b Physical & Theoretical Chemistry Laboratory, South Parks Road, Oxford, UK

Abstract

The first examples of halogen bonding redox-active ferrocene receptors and their anion electrochemical sensing properties are reported. Halogen bonding was found to significantly amplify the magnitude of the receptor's metallocene redox-couple's voltammetric responses for halide sensing compared to their hydrogen bonding analogues in both acetonitrile and aqueous–acetonitrile solvent media.

This article is part of the themed collection: In celebration of Paul Beer’s 60th Birthday

Download options Please wait...

Supplementary files

Supplementary information PDF (2236K)

Article information

DOI: https://doi.org/10.1039/C5CC05704C
Article type: Communication
Submitted: 09 ⵢⵓⵍ 2015
Accepted: 05 ⵖⵓⵛ 2015
First published: 06 ⵖⵓⵛ 2015

Download Citation

Chem. Commun., 2015,51, 14640-14643

Permissions

Request permissions

Halogen bonding-enhanced electrochemical halide anion sensing by redox-active ferrocene receptors

J. Y. C. Lim, M. J. Cunningham, J. J. Davis and P. D. Beer, Chem. Commun., 2015, 51, 14640 DOI: 10.1039/C5CC05704C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Halogen bonding-enhanced electrochemical halide anion sensing by redox-active ferrocene receptors†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Halogen bonding-enhanced electrochemical halide anion sensing by redox-active ferrocene receptors

Social activity

Search articles by author

Spotlight

Advertisements