Issue 5, 2007

Tuning the strength and selectivity of ion-pair recognition using heteroditopic calix[4]arene-based receptors

Abstract

The syntheses, characterisation and ion binding properties of two novel heteroditopic calix[4]arene receptors are reported. These systems were found to demonstrate cooperative binding of certain ion-pairs, with the selectivity depending critically on the structure of the receptors. Furthermore, a macrocyclic effect for ion-pair recognition was observed to operate.

Graphical abstract: Tuning the strength and selectivity of ion-pair recognition using heteroditopic calix[4]arene-based receptors

Supplementary files

Article information

Article type
Paper
Submitted
01 ⵏⵓⵡ 2006
Accepted
28 ⵏⵓⵡ 2006
First published
20 ⴷⵓⵊ 2006

New J. Chem., 2007,31, 684-690

Tuning the strength and selectivity of ion-pair recognition using heteroditopic calix[4]arene-based receptors

M. D. Lankshear, I. M. Dudley, K. Chan and P. D. Beer, New J. Chem., 2007, 31, 684 DOI: 10.1039/B615873K

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