Issue 26, 2022

A Raman optical activity spectrometer can sensitively detect lanthanide circularly polarized luminescence

Abstract

Recently, many studies have appeared in which the Raman optical activity (ROA) instrument was found to be convenient for measuring circularly polarized luminescence (CPL). Typically, weak lanthanide luminescence including circular polarization could be detected. The new detection scheme is referred to as ROA-CPL spectroscopy. It is particularly useful when also the vibrational (ROA) itself is detectable as the molecule structure can be examined more reliably. In this review, development of this chiroptical approach and its applications in structural studies of biomolecules are summarized.

Graphical abstract: A Raman optical activity spectrometer can sensitively detect lanthanide circularly polarized luminescence

  • This article is part of the themed collection: PCCP Reviews

Article information

Article type
Perspective
Submitted
08 ⵉⴱⵔ 2022
Accepted
28 ⵎⴰⵢ 2022
First published
31 ⵎⴰⵢ 2022

Phys. Chem. Chem. Phys., 2022,24, 15672-15686

A Raman optical activity spectrometer can sensitively detect lanthanide circularly polarized luminescence

T. Wu, Phys. Chem. Chem. Phys., 2022, 24, 15672 DOI: 10.1039/D2CP01641A

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