Issue 22, 2020

Applications of diazaphospholene hydrides in chemical catalysis

Abstract

Diazaphospholenes have recently emerged as main-group hydride transfer catalysts. This review will briefly summarize the common structural variants of diazaphospholenes, and the properties that make them superb hydride transfer catalysts, followed by a critical examination of the various preparative routes toward diazaphospholenes. Finally, an in-depth examination of the reactivity of diazaphospholenes in contemporary catalysis, including asymmetric catalysis will be undertaken.

Graphical abstract: Applications of diazaphospholene hydrides in chemical catalysis

Article information

Article type
Review Article
Submitted
01 ⵎⴰⵢ 2020
First published
20 ⴽⵜⵓ 2020

Chem. Soc. Rev., 2020,49, 8335-8353

Applications of diazaphospholene hydrides in chemical catalysis

A. W. H. Speed, Chem. Soc. Rev., 2020, 49, 8335 DOI: 10.1039/D0CS00476F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements