Issue 16, 2019

Recent advances in Fe-catalyzed C–H aminations using azides as nitrene precursors

Abstract

Intramolecular aminations of C–H bonds represent an elegant synthetic way to form important N-heterocycles. If suitable nitrene precursors are employed, organometallic complexes are able to catalyze the C–H amination under mild conditions. In the past years, Fe catalysis has emerged as a vigorously developing new (old) discipline. The present review highlights the most important developments in this field through a systematic differentiation between open-shell (radical) and closed-shell (non-radical) mechanisms.

Graphical abstract: Recent advances in Fe-catalyzed C–H aminations using azides as nitrene precursors

Article information

Article type
Minireview
Submitted
09 ⵉⴱⵔ 2019
Accepted
03 ⵢⵓⵍ 2019
First published
03 ⵢⵓⵍ 2019

Catal. Sci. Technol., 2019,9, 4188-4197

Recent advances in Fe-catalyzed C–H aminations using azides as nitrene precursors

B. Plietker and A. Röske, Catal. Sci. Technol., 2019, 9, 4188 DOI: 10.1039/C9CY00675C

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