Issue 18, 2018
From the journal:

Organic Chemistry Frontiers

The mechanism of the excited-state multiple proton transfer reaction for 3-Me-2,6-diazaindole in aqueous solution†

Jin-Dou Huang ORCID logo bc  and  Huipeng Ma ORCID logo *a  

* Corresponding authors

a College of Medical Laboratory Science, Dalian Medical University, Dalian 116044, P. R. China
E-mail: hpma@dlmedu.edu.cn

b Key Laboratory of New Energy and Rare Earth Resource Utilization of State Ethnic Affairs Commission, Key Laboratory of Photosensitive Materials and Devices of Liaoning Province, School of Physics and Materials Engineering, Dalian Nationalities University, Dalian 116600, P. R. China

c State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China

Abstract

The optical properties of 3-Me-2,6-diazaindole in aqueous solution were simulated and then found to compare well with experimental data. Furthermore, the ground state and exited state potential energy surfaces for 3-Me-2,6-diazaindole + L3H2O were constructed, and a new three water molecules-assisted exited state quadruple proton transfer mechanism is proposed.

Graphical abstract: The mechanism of the excited-state multiple proton transfer reaction for 3-Me-2,6-diazaindole in aqueous solution

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Article information

DOI
https://doi.org/10.1039/C8QO00628H
Article type
Research Article
Submitted
27 ⵢⵓⵏ 2018
Accepted
07 ⵖⵓⵛ 2018
First published
08 ⵖⵓⵛ 2018

Org. Chem. Front., 2018,5, 2749-2753

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The mechanism of the excited-state multiple proton transfer reaction for 3-Me-2,6-diazaindole in aqueous solution

J. Huang and H. Ma, Org. Chem. Front., 2018, 5, 2749 DOI: 10.1039/C8QO00628H

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