Issue 6, 2018

Teaching an old molecule new tricks: evidence and rationalisation of the slow magnetisation dynamics in [DyTp2Acac]

Abstract

We report the luminescence and magnetic properties of the mononuclear Dy(III) complex [DyTp2Acac] (Tp = tris-pyrazolylborohydride and Acac = 2,4-pentanedionate). This complex displays peculiar slow magnetisation dynamics at low temperature in the absence of a static field, which we managed to interpret using its resolved luminescence spectrum and ab initio calculations.

Graphical abstract: Teaching an old molecule new tricks: evidence and rationalisation of the slow magnetisation dynamics in [DyTp2Acac]

Supplementary files

Article information

Article type
Research Article
Submitted
25 ⴱⵕⴰ 2018
Accepted
03 ⵉⴱⵔ 2018
First published
04 ⵉⴱⵔ 2018

Inorg. Chem. Front., 2018,5, 1346-1353

Teaching an old molecule new tricks: evidence and rationalisation of the slow magnetisation dynamics in [DyTp2Acac]

F. Guégan, F. Riobé, O. Maury, J. Jung, B. Le Guennic, C. Morell and D. Luneau, Inorg. Chem. Front., 2018, 5, 1346 DOI: 10.1039/C8QI00174J

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