Issue 32, 2018

Redox behaviour of ([fc(NPiPr2)2]Fe)2, formation of an iron–iron bond and cleavage of azobenzene

Abstract

The redox behaviour of the dimeric tetrairon complex, ([fc(NPiPr2)2]Fe)2 (where fc(NPiPr2)2 = 1,1′-(C5H4NPiPr2)2Fe) has been investigated. Upon reduction with KC8 an Fe–Fe bond is formed with the complex maintaining a high spin configuration and having the formula [K(THF)6]([fc(NPiPr2)2]Fe)2. In contrast, oxidation of the complex is ligand based; for example, addition of the 1,2-diiodoethane (I2 equivalent) results in the formation of the monomeric iron(II) diiodide [fc(NiPr2I)2]FeI2 wherein the phosphine is oxidized. The dimeric tetrairon complex reacts photolytically with azobenzene, cleaving the N[double bond, length as m-dash]N double bond and forming the new monomeric bis(phosphoramidate) iron complex. [fc(NP(NPh)iPr2)2]Fe. Characterization of these paramagnetic complexes was accomplished by magnetic susceptibility studies and X-ray analyses.

Graphical abstract: Redox behaviour of ([fc(NPiPr2)2]Fe)2, formation of an iron–iron bond and cleavage of azobenzene

Supplementary files

Article information

Article type
Paper
Submitted
03 ⵎⴰⵕ 2018
Accepted
26 ⵢⵓⵏ 2018
First published
26 ⵢⵓⵏ 2018

Dalton Trans., 2018,47, 10925-10931

Redox behaviour of ([fc(NPiPr2)2]Fe)2, formation of an iron–iron bond and cleavage of azobenzene

F. S. Pick, D. B. Leznoff and M. D. Fryzuk, Dalton Trans., 2018, 47, 10925 DOI: 10.1039/C8DT00828K

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