Issue 67, 2018

Diels–Alder reactions of “in situ” generated perfluorinated thioketones

Abstract

A simple and general procedure for the preparation of Diels–Alder adducts of perfluorinated thioketones and various dienes is reported. The corresponding Diels–Alder adducts were prepared in 30–78% yield under mild conditions via a reaction of a mixture of fluoroolefins, sulfur, diene and CsF as a catalyst.

Graphical abstract: Diels–Alder reactions of “in situ” generated perfluorinated thioketones

Supplementary files

Article information

Article type
Communication
Submitted
26 ⵢⵓⵏ 2018
Accepted
24 ⵢⵓⵍ 2018
First published
01 ⵖⵓⵛ 2018

Chem. Commun., 2018,54, 9298-9300

Diels–Alder reactions of “in situ” generated perfluorinated thioketones

V. Petrov, A. A. Marchione and R. Dooley, Chem. Commun., 2018, 54, 9298 DOI: 10.1039/C8CC05075A

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