Issue 18, 2018
From the journal:

Chemical Communications

Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction†

Vladimir O. Smirnov, ORCID logo a   Anton S. Maslov,ab   Vladimir A. Kokorekin,ac   Alexander A. Korlyukovde  and  Alexander D. Dilman ORCID logo *a  

* Corresponding authors

a N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation

b Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow, Russian Federation

c I. M. Sechenov First Moscow State Medical University, Trubetskaya st. 8-2, 119991 Moscow, Russian Federation

d A. N. Nesmeyanov Institute of Organoelement Compounds, Vavilov str. 28, 119991 Moscow, Russian Federation

e N. I. Pirogov Russian National Research Medical University, Ostrovitianov str., 1, 117997 Moscow, Russian Federation

Abstract

A method for the generation of the CF3 radical from CF3-substituted borate complexes bearing a pyridine-N-oxide ligand is described. Cleavage of the C–B bond occurs via single electron reduction by a Cu(I) photocatalyst activated by visible light.

Graphical abstract: Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction

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Article information

DOI
https://doi.org/10.1039/C8CC00245B
Article type
Communication
Submitted
11 ⵉⵏⵏ 2018
Accepted
05 ⴱⵕⴰ 2018
First published
05 ⴱⵕⴰ 2018

Chem. Commun., 2018,54, 2236-2239

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Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction

V. O. Smirnov, A. S. Maslov, V. A. Kokorekin, A. A. Korlyukov and A. D. Dilman, Chem. Commun., 2018, 54, 2236 DOI: 10.1039/C8CC00245B

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