Issue 38, 2016

Copper-catalyzed N-formylation of amines with CO2 under ambient conditions

Abstract

We carried out work on N-formylation of amines with CO2 and PhSiH3 to produce formamides catalyzed by a copper complex. It was found that the Cu(OAc)2–bis(diphenylphosphino)ethane (dppe) catalytic system was very efficient for these kind of reactions at room temperature and 1 atm CO2 with only 0.1 mol% catalyst loading.

Graphical abstract: Copper-catalyzed N-formylation of amines with CO2 under ambient conditions

Supplementary files

Article information

Article type
Communication
Submitted
27 ⴱⵕⴰ 2016
Accepted
23 ⵎⴰⵕ 2016
First published
24 ⵎⴰⵕ 2016

RSC Adv., 2016,6, 32370-32373

Copper-catalyzed N-formylation of amines with CO2 under ambient conditions

S. Zhang, Q. Mei, H. Liu, H. Liu, Z. Zhang and B. Han, RSC Adv., 2016, 6, 32370 DOI: 10.1039/C6RA05199E

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