Issue 78, 2015

Halogen bonding-enhanced electrochemical halide anion sensing by redox-active ferrocene receptors

Abstract

The first examples of halogen bonding redox-active ferrocene receptors and their anion electrochemical sensing properties are reported. Halogen bonding was found to significantly amplify the magnitude of the receptor's metallocene redox-couple's voltammetric responses for halide sensing compared to their hydrogen bonding analogues in both acetonitrile and aqueous–acetonitrile solvent media.

Graphical abstract: Halogen bonding-enhanced electrochemical halide anion sensing by redox-active ferrocene receptors

Supplementary files

Article information

Article type
Communication
Submitted
09 ⵢⵓⵍ 2015
Accepted
05 ⵖⵓⵛ 2015
First published
06 ⵖⵓⵛ 2015

Chem. Commun., 2015,51, 14640-14643

Halogen bonding-enhanced electrochemical halide anion sensing by redox-active ferrocene receptors

J. Y. C. Lim, M. J. Cunningham, J. J. Davis and P. D. Beer, Chem. Commun., 2015, 51, 14640 DOI: 10.1039/C5CC05704C

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