Issue 45, 2014

Ester-substituted cyclometallated rhodium and iridium coordination assemblies with π-bonded dioxolene ligand: synthesis, structures and luminescent properties

Abstract

A series of functionalized cyclometallated rhodium and iridium coordination assemblies 2–7 displaying a π-bonded dioxolene ligand is described. The X-ray molecular structures of two of the above compounds showed the formation of a 1D supramolecular chain mediated by π–π interactions among individual units. The luminescent properties of these compounds are presented and discussed. These results show that the stacking interactions are retained also in solution and emission from excited dimeric species is observed.

Graphical abstract: Ester-substituted cyclometallated rhodium and iridium coordination assemblies with π-bonded dioxolene ligand: synthesis, structures and luminescent properties

Supplementary files

Article information

Article type
Paper
Submitted
10 ⴱⵕⴰ 2014
Accepted
14 ⵎⴰⵢ 2014
First published
05 ⵢⵓⵏ 2014

RSC Adv., 2014,4, 23740-23748

Author version available

Ester-substituted cyclometallated rhodium and iridium coordination assemblies with π-bonded dioxolene ligand: synthesis, structures and luminescent properties

A. Damas, H. Sesolis, M. N. Rager, L. M. Chamoreau, M. P. Gullo, A. Barbieri and H. Amouri, RSC Adv., 2014, 4, 23740 DOI: 10.1039/C4RA01185F

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