Issue 32, 2014

An octahedral aluminium(iii) complex as a three-fold node for supramolecular heterometallic self-assemblies: solution and solid state chemistry

Abstract

The new ditopic ligand LH (L = 3-(pyridin-4-ylmethyl)acetylacetonate) has been prepared. The crystal structure of the aluminium(III) complex AlL3·H2O is reported and shows three pendant pyridyl groups available for bridging metal ions. With square planar ions (Cu(II), Pd(II)) the formation of a symmetric cage complex [M6(AlL3)8]12+ is proposed. With Co(NCS)2 an extended structure [{Co(NCS)2}(AlL3)(OH2)]n is found. Factors favouring cage or extended structures are briefly discussed.

Graphical abstract: An octahedral aluminium(iii) complex as a three-fold node for supramolecular heterometallic self-assemblies: solution and solid state chemistry

Supplementary files

Article information

Article type
Paper
Submitted
20 ⵉⵏⵏ 2014
Accepted
17 ⵎⴰⵕ 2014
First published
03 ⵉⴱⵔ 2014

RSC Adv., 2014,4, 16686-16693

Author version available

An octahedral aluminium(III) complex as a three-fold node for supramolecular heterometallic self-assemblies: solution and solid state chemistry

D. Simond, S. E. Clifford, A. F. Vieira, C. Besnard and A. F. Williams, RSC Adv., 2014, 4, 16686 DOI: 10.1039/C4RA00575A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements