Issue 26, 2011

Activation of olefins with low-valent gallium compounds under ambient conditions

Abstract

The reactions of Ar′GaGaAr′ (Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2) with alkenes revealed the addition of two olefins per Ar′GaGaAr′ under ambient conditions for ethylene, propene, 1-hexene and styrene but no reactions with more hindered or cyclic olefins.

Graphical abstract: Activation of olefins with low-valent gallium compounds under ambient conditions

Supplementary files

Article information

Article type
Communication
Submitted
23 ⵎⴰⵕ 2011
Accepted
05 ⵎⴰⵢ 2011
First published
31 ⵎⴰⵢ 2011

Chem. Commun., 2011,47, 7506-7508

Activation of olefins with low-valent gallium compounds under ambient conditions

C. A. Caputo, Z. Zhu, Z. D. Brown, J. C. Fettinger and P. P. Power, Chem. Commun., 2011, 47, 7506 DOI: 10.1039/C1CC11676B

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