Surface functionalization of conjugated microporous polymer thin films and nanomembranes using orthogonal chemistries

P. Lindemann; A. Schade; L. Monnereau; W. Feng; K. Batra; H. Gliemann; P. Levkin; S. Bräse; C. Wöll; M. Tsotsalas

doi:10.1039/C5TA09429A

Surface functionalization of conjugated microporous polymer thin films and nanomembranes using orthogonal chemistries†

P. Lindemann,^a A. Schade,^b L. Monnereau,^b W. Feng,^c K. Batra,^a H. Gliemann,^a P. Levkin,^c S. Bräse,^bc C. Wöll^a and M. Tsotsalas*^a

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^a Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344 Eggenstein-Leopoldshafen, Germany
E-mail: manuel.tsotsalas@kit.edu

^b Institute for Organic Chemistry (IOC), Karlsruhe Institute of Technology (KIT), 76131 Karlsruhe, Germany

^c Institute of Toxicology and Genetics (ITG), Karlsruhe Institute of Technology (KIT), 76344 Eggenstein-Leopoldshafen, Germany

Abstract

Conjugated microporous polymers (CMP) have attracted large interest due to their intrinsic porosity, outstanding stability and high variability. Here we present the surface modification of CMP thin films and nanomembranes via orthogonal chemistry. Using the light induced thiol–yne reaction for the functionalization provides the additional opportunity to photo-pattern the CMP materials.

This article is part of the themed collection: Emerging Investigators 2016: Novel design strategies for new functional materials

Journal of Materials Chemistry A

Surface functionalization of conjugated microporous polymer thin films and nanomembranes using orthogonal chemistries†

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Surface functionalization of conjugated microporous polymer thin films and nanomembranes using orthogonal chemistries

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