Issue 2, 2015

Fabrication of a nitrogen-doped graphene quantum dot from MOF-derived porous carbon and its application for highly selective fluorescence detection of Fe3+

Abstract

Nitrogen doping of carbon quantum dots results in improved fluorescence performance and a wider range of applications in photocatalysis, sensors, bioimaging, etc. Herein, a water-soluble and well-crystallized nitrogen-doped graphene quantum dot (N-GQD) has been obtained by using a MOF-derived carbon (ZIF-8C) as a new source of graphitic sheets. The preparation is based on a rapid, eco-friendly and efficient acid vapour cutting strategy, which is different from previously reported solution chemistry routes. The as-prepared N-GQD is photoluminescent and exhibits an excitation-independent behaviour. Because of the presence of O-functional groups on the surface, the obtained N-GQD can serve as a fluorescent sensing probe for highly selective detection of Fe3+ ions with a detection limit of 0.08 μM (at a signal-to-noise ratio of 3). This work would enable new opportunities for the wider use of MOF-based materials and also contribute to the fluorescent analysis of Fe3+.

Graphical abstract: Fabrication of a nitrogen-doped graphene quantum dot from MOF-derived porous carbon and its application for highly selective fluorescence detection of Fe3+

Supplementary files

Article information

Article type
Paper
Submitted
05 ⵛⵓⵜ 2014
Accepted
30 ⴽⵜⵓ 2014
First published
03 ⵏⵓⵡ 2014

J. Mater. Chem. C, 2015,3, 291-297

Author version available

Fabrication of a nitrogen-doped graphene quantum dot from MOF-derived porous carbon and its application for highly selective fluorescence detection of Fe3+

H. Xu, S. Zhou, L. Xiao, H. Wang, S. Li and Q. Yuan, J. Mater. Chem. C, 2015, 3, 291 DOI: 10.1039/C4TC01991A

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