Reductive deoxygenation of CO2 by a bimetallic titanium bis(pentalene) complex

Alexander F. R. Kilpatrick; F. Geoffrey N. Cloke

doi:10.1039/C3CC48379G

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Reductive deoxygenation of CO₂ by a bimetallic titanium bis(pentalene) complex†

Alexander F. R. Kilpatrick^a and F. Geoffrey N. Cloke*^a

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^a Department of Chemistry, School of Life Sciences, University of Sussex, Brighton, UK
E-mail: f.g.cloke@sussex.ac.uk
Fax: +44 (0)1273 876 687

Abstract

The bimetallic bis(pentalene) complex (μ:η⁵,η⁵-Pn^†)₂Ti₂ reductively splits CO₂ to form a bis(oxo) bridged dimer [(η⁸-Pn^†)Ti(μ-O)]₂, in which the Ti–Ti bond has been cleaved, and the dicarbonyl complex (μ:η⁵,η⁵-Pn^†)₂[Ti(CO)]₂.

This article is part of the themed collections: Geoff Cloke at 65: a pioneer in organometallic chemistry and Metal-Mediated Transformations of Small Molecules

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Article information

DOI: https://doi.org/10.1039/C3CC48379G
Article type: Communication
Submitted: 01 ⵏⵓⵡ 2013
Accepted: 17 ⵉⵏⵏ 2014
First published: 17 ⵉⵏⵏ 2014

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Chem. Commun., 2014,50, 2769-2771

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Reductive deoxygenation of CO₂ by a bimetallic titanium bis(pentalene) complex

A. F. R. Kilpatrick and F. G. N. Cloke, Chem. Commun., 2014, 50, 2769 DOI: 10.1039/C3CC48379G

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