Issue 12, 2006

Mechanism of cellulose dissolution in the ionic liquid1-n-butyl-3-methylimidazolium chloride: a 13C and 35/37Cl NMR relaxation study on model systems

Abstract

13C and 35/37Cl NMR relaxation measurements on several model systems demonstrate that the solvation of cellulose by the ionic liquid (IL) 1-n-butyl-3-methylimidazolium chloride ([C4mim]Cl) involves hydrogen-bonding between the carbohydrate hydroxyl protons and the IL chloride ions in a 1 ∶ 1 stoichiometry.

Graphical abstract: Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a 13C and 35/37Cl NMR relaxation study on model systems

Supplementary files

Article information

Article type
Communication
Submitted
27 ⴷⵓⵊ 2005
Accepted
23 ⵉⵏⵏ 2006
First published
09 ⴱⵕⴰ 2006

Chem. Commun., 2006, 1271-1273

Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a 13C and 35/37Cl NMR relaxation study on model systems

R. C. Remsing, R. P. Swatloski, R. D. Rogers and G. Moyna, Chem. Commun., 2006, 1271 DOI: 10.1039/B600586C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements