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A biomimetic di-μ-oxo dimanganese complex bearing two triazole-binding tridentate ligands is successfully anchored inside a metal–organic framework (MOF) through a covalent-functionalization-assisted coordination strategy, exhibiting high activity and reliable durability in the chemical water oxidation reaction.

Graphical abstract: A high-valent di-μ-oxo dimanganese complex covalently anchored in a metal–organic framework as a highly efficient and recoverable water oxidation catalyst

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