Cu-mediated solid-state reaction in a post-functionalized metal–organic framework

Marie Savonnet; Jérôme Canivet; Serge Gambarelli; Lionel Dubois; Delphine Bazer-Bachi; Vincent Lecocq; Nicolas Bats; David Farrusseng

doi:10.1039/C2CE00017B

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Cu-mediated solid-state reaction in a post-functionalized metal–organic framework†

Marie Savonnet,^a Jérôme Canivet,^a Serge Gambarelli,^b Lionel Dubois,^c Delphine Bazer-Bachi,^d Vincent Lecocq,^d Nicolas Bats^d and David Farrusseng*^a

Author affiliations

* Corresponding authors

^a IRCELYON, University of Lyon 1—CNRS, 2 avenue Albert Einstein, Villeurbanne Cedex, France
E-mail: david.farrusseng@ircelyon.univ-lyon1.fr
Fax: (+33) 4 72 44 54 36

^b CEA, INAC, SCIB, Laboratoire de Résonance Magnétique (UMR-E 3 CEA-UJF), 17 rue des Martyrs, 38054 Grenoble Cedex 09, France

^c CEA, INAC, SCIB, Laboratoire de Reconnaissance Ionique (UMR-E 3 CEA-UJF), 17 rue des Martyrs, 38054 Grenoble Cedex 09, France

^d IFP Energies Nouvelles, BP n°3, Solaize, France

Abstract

We serendipitously found that a functionalized MOF containing grafted copper species can react with itself without solvent in order to modify the chemical functions present on its walls. The use of EPR techniques allows new insight into the copper-mediated azide reduction.

This article is part of the themed collection: Postsynthetic modification of coordination networks

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Article information

DOI: https://doi.org/10.1039/C2CE00017B
Article type: Communication
Submitted: 05 Jan 2012
Accepted: 29 Feb 2012
First published: 01 Mar 2012

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CrystEngComm, 2012,14, 4105-4108

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Cu-mediated solid-state reaction in a post-functionalized metal–organic framework

M. Savonnet, J. Canivet, S. Gambarelli, L. Dubois, D. Bazer-Bachi, V. Lecocq, N. Bats and D. Farrusseng, CrystEngComm, 2012, 14, 4105 DOI: 10.1039/C2CE00017B

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CrystEngComm

Cu-mediated solid-state reaction in a post-functionalized metal–organic framework†

Abstract

Supplementary files

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Cu-mediated solid-state reaction in a post-functionalized metal–organic framework

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